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金属有机催化剂中，配体发挥着关键作用，不同的配体通过稳定及激活中心金属原子，能够在催化反应中发挥选择性的催化作用。
根据给体原子或子结构的差异分为：膦配体/ Phosphine Ligands、Salen配体/ Salen Ligands、氮杂环卡宾配体/ N-Heterocyclic Carbene Ligands、烯配体/ Ene Ligands、二酮配体/ Diketone Ligands、胺配体/ Amine Ligands、亚胺配体/ Imine Ligands、吡啶配体/ Pyridine Ligands、联吡啶,三联吡啶配体/ Bipyridine & Terpyridine Ligands、菲咯啉配体/ Phenanthroline Ligands；
在以上多种配体中，膦配体在偶联反应中扮演者最为广泛且重要的作用，如经典的Suzuki Coupling、Stille Coupling、Negishi Coupling、Heck Reaction；
T818715 三叔丁基膦, 1.0 M in toluene
Stille Coupling Made Easier-The Synergic Effect of Copper(I) Salts and the Fluoride Ion
S. P. H. Mee, V. Lee, J. E. Baldwin, Angew. Chem. Int. Ed., 2004, 43, 1132-1136.
T818895 三苯基膦, >99.0%(GC)
Ligand Effects on Negishi Couplings of Alkenyl Halides
A. Krasovskiy, B. H. Lipshutz, Org. Lett., 2011, 13, 3818-3821.
D806412 2-二环己膦基-2'-(N,N-二甲胺)-联苯(Dave-Phos), 98%
Palladium-Catalyzed Heck Reaction of Aryl Chlorides under Mild Conditions Promoted by Organic Ionic Bases
H.-J. Xu, Y.-Q. Zhao, X.-F. Zhou, J. Org. Chem., 2011, 76, 8036-8041.
| 产品编号 | 结构式 | 项目名称规格 | 分子式 | 加入购物车 |
|---|---|---|---|---|
| T818895 |
| 三苯基膦, >99.0%(GC) Triphenylphosphine, >99.0%(GC) |
C18H15P | |
| T819087 |
| 三正辛基膦, 90% Trioctylphosphine, 90% |
C24H51P | |
| D854491 |
| 二邻甲苯基氯化膦, 98% Di-o-tolylchlorophosphine, 98% |
C14H14ClP | |
| B801963 |
| 1,1'-双(二苯基膦)二茂铁, 97% 1,1'-Bis(diphenylphosphino)ferrocene, 97% |
C34H28FeP2 | |
| B802796 |
| (±)-2,2'-双-(二苯膦基)-1,1'-联萘, 98% (±)-BINAP, 98% |
C44H32P2 | |
| X820583 |
| 4,5-双二苯基膦-9,9-二甲基氧杂蒽, 98% Xantphos, 98% |
C39H32OP2 | |
| T818719 |
| 三丁基膦, 98% Tributylphosphine, 98% |
C12H27P | |
| T818715 |
| 三叔丁基膦, 1.0 M in toluene Tri-tert-butylphosphine, 1.0 M in toluene |
C12H27P | |
| T819653 |
| 三(2-呋喃基)膦, 98% Tri(2-furyl)phosphine, 98% |
C12H9O3P | |
| B802401 |
| 1,4-双(二苯膦基)丁烷, 98% 1,4-Bis(diphenylphosphino)butane, 98% |
C28H28P2 | |
| B801885 |
| 1,2-双(二苯基膦)乙烷, 98% 1,2-Bis(diphenylphosphino)ethane, 98% |
C26H24P2 | |
| T819825 |
| 三环己基膦, 96% Tricyclohexyl phosphine, 96% |
C18H33P | |
| B822229 |
| (2-溴苯基)二苯基膦, ≥98% (2-BROMOPHENYL)DIPHENYLPHOSPHIN, ≥98% |
C18H14BrP | |
| C805066 |
| 氯代二苯基膦, 97% Chlorodiphenylphosphine, 97% |
C12H10ClP | |
| T819166 |
| 三(2-羧乙基)膦盐酸盐, 98% Tris(2-carboxyethyl)phosphine hydrochloride, 98% |
C9H15O6P·HCl | |
| D806864 |
| 2-双环己基膦-2',6'-二甲氧基联苯, 98% 2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl, 98% |
C26H35O2P | |
| D807807 |
| 2-双环己基膦-2 ',6'-二异丙氧基联苯, 98% 2-Dicyclohexylphosphino-2',6'-diisopropoxybiphenyl, 98% |
C30H43O2P | |
| T819389 |
| 三(2-甲苯基)膦, 97% Tri(o-tolyl)phosphine, 97% |
C21H21P | |
| B801884 |
| 双(二苯基膦)甲烷, 98% Bis(diphenylphosphino)methane, 98% |
C25H22P2 | |
| B802795 |
| 1,3-双(二苯膦基)丙烷, 97% 1,3-Bis(diphenylphosphino)propane, 97% |
C27H26P2 |
